Nano 'hall of mirrors' causes molecules to mix with light

When a molecule emits a blink of light, it doesn't expect it to ever come back. However researchers have now managed to place single molecules in such a tiny optical cavity that emitted photons, or particles of light, return to the molecule before they have properly left. The energy oscillates back and forth between light and molecule, resulting in a complete mixing of the two.

Previous attempts to mix molecules with light have been complex to produce and only achievable at very low temperatures, but the researchers, led by the University of Cambridge, have developed a method to produce these 'half-light' molecules at room temperature.

These unusual interactions of molecules with light provide new ways to manipulate the physical and chemical properties of matter, and could be used to process quantum information, aid in the understanding of complex processes at work in photosynthesis, or even manipulate the chemical bonds between atoms. The results are reported in the journal Nature.

To use single molecules in this way, the researchers had to reliably construct cavities only a billionth of a metre (one nanometre) across in order to trap light. They used the tiny gap between a gold nanoparticle and a mirror, and placed a coloured dye molecule inside.

"It's like a hall of mirrors for a molecule, only spaced a hundred thousand times thinner than a human hair," said Professor Jeremy Baumberg of the NanoPhotonics Centre at Cambridge's Cavendish Laboratory, who led the research.

In order to achieve the molecule-light mixing, the dye molecules needed to be correctly positioned in the tiny gap. "Our molecules like to lie down flat on the gold, and it was really hard to persuade them to stand up straight," said Rohit Chikkaraddy, lead author of the study.

To solve this, the team joined with a team of chemists at Cambridge led by Professor Oren Scherman to encapsulate the dyes in hollow barrel-shaped molecular cages called cucurbiturils, which are able to hold the dye molecules in the desired upright position.

When assembled together correctly, the molecule scattering spectrum splits into two separated quantum states which is the signature of this 'mixing'. This spacing in colour corresponds to photons taking less than a trillionth of a second to come back to the molecule.

A key advance was to show strong mixing of light and matter was possible for single molecules even with large absorption of light in the metal and at room temperature. "Finding single-molecule signatures took months of data collection," said Chikkaraddy.

The researchers were also able to observe steps in the colour spacing of the states corresponding to whether one, two, or three molecules were in the gap.

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The Cambridge team collaborated with theorists Professor Ortwin Hess at the Blackett Laboratory, Imperial College London and Dr Edina Rosta at Kings College London to understand the confinement and interaction of light in such tiny gaps, matching experiments amazingly well.

Reference:

Single-molecule strong coupling at room temperature in plasmonic nanocavities
Nature (2016) doi:10.1038/nature17974

University of Cambridge

Scientists 'squeeze' light one particle at a time

A team of scientists has successfully measured particles of light being "squeezed", in an experiment that had been written off in physics textbooks as impossible to observe.

Squeezing is a strange phenomenon of quantum physics. It creates a very specific form of light which is "low-noise" and is potentially useful in technology designed to pick up faint signals, such as the detection of gravitational waves.

The standard approach to squeezing light involves firing an intense laser beam at a material, usually a non-linear crystal, which produces the desired effect.

For more than 30 years, however, a theory has existed about another possible technique. This involves exciting a single atom with just a tiny amount of light. The theory states that the light scattered by this atom should, similarly, be squeezed.

Unfortunately, although the mathematical basis for this method - known as squeezing of resonance fluorescence - was drawn up in 1981, the experiment to observe it was so difficult that one established quantum physics textbook despairingly concludes: "It seems hopeless to measure it".

So it has proven - until now. In the journal Nature, a team of physicists report that they have successfully demonstrated the squeezing of individual light particles, or photons, using an artificially constructed atom, known as a semiconductor quantum dot. Thanks to the enhanced optical properties of this system and the technique used to make the measurements, they were able to observe the light as it was scattered, and proved that it had indeed been squeezed.

Professor Mete Atature, a Fellow of St John's College at the University of Cambridge, who led the research, said: "It's one of those cases of a fundamental question that theorists came up with, but which, after years of trying, people basically concluded it is impossible to see for real - if it's there at all."

"We managed to do it because we now have artificial atoms with optical properties that are superior to natural atoms. That meant we were able to reach the necessary conditions to observe this fundamental property of photons and prove that this odd phenomenon of squeezing really exists at the level of a single photon. It's a very bizarre effect that goes completely against our senses and expectations about what photons should do."

Like a lot of quantum physics, the principles behind squeezing light involve some mind-boggling concepts.

It begins with the fact that wherever there are light particles, there are also associated electromagnetic fluctuations. This is a sort of static which scientists refer to as "noise". Typically, the more intense light gets, the higher the noise. Dim the light, and the noise goes down.

But strangely, at a very fine quantum level, the picture changes. Even in a situation where there is no light, electromagnetic noise still exists. These are called vacuum fluctuations. While classical physics tells us that in the absence of a light source we will be in perfect darkness, quantum mechanics tells us that there is always some of this ambient fluctuation.

"If you look at a flat surface, it seems smooth and flat, but we know that if you really zoom in to a super-fine level, it probably isn't perfectly smooth at all," Atature said. "The same thing is happening with vacuum fluctuations. Once you get into the quantum world, you start to get this fine print. It looks like there are zero photons present, but actually there is just a tiny bit more than nothing."

Importantly, these vacuum fluctuations are always present and provide a base limit to the noise of a light field. Even lasers, the most perfect light source known, carry this level of fluctuating noise.

This is when things get stranger still, however, because, in the right quantum conditions, that base limit of noise can be lowered even further. This lower-than-nothing, or lower-than-vacuum, state is what physicists call squeezing.

In the Cambridge experiment, the researchers achieved this by shining a faint laser beam on to their artificial atom, the quantum dot. This excited the quantum dot and led to the emission of a stream of individual photons. Although normally, the noise associated with this photonic activity is greater than a vacuum state, when the dot was only excited weakly the noise associated with the light field actually dropped, becoming less than the supposed baseline of vacuum fluctuations.

Explaining why this happens involves some highly complex quantum physics. At its core, however, is a rule known as Heisenberg's uncertainty principle. This states that in any situation in which a particle has two linked properties, only one can be measured and the other must be uncertain.

In the normal world of classical physics, this rule does not apply. If an object is moving, we can measure both its position and momentum, for example, to understand where it is going and how long it is likely to take getting there. The pair of properties - position and momentum - are linked.

In the strange world of quantum physics, however, the situation changes. Heisenberg states that only one part of a pair can ever be measured, and the other must remain uncertain.

In the Cambridge experiment, the researchers used that rule to their advantage, creating a tradeoff between what could be measured, and what could not. By scattering faint laser light from the quantum dot, the noise of part of the electromagnetic field was reduced to an extremely precise and low level, below the standard baseline of vacuum fluctuations. This was done at the expense of making other parts of the electromagnetic field less measurable, meaning that it became possible to create a level of noise that was lower-than-nothing, in keeping with Heisenberg's uncertainty principle, and hence the laws of quantum physics.

Plotting the uncertainty with which fluctuations in the electromagnetic field could be measured on a graph creates a shape where the uncertainty of one part has been reduced, while the other has been extended. This creates a squashed-looking, or "squeezed" shape, hence the term, "squeezing" light.

Atature added that the main point of the study was simply to attempt to see this property of single photons, because it had never been seen before. "It's just the same as wanting to look at Pluto in more detail or establishing that pentaquarks are out there," he said. "Neither of those things has an obvious application right now, but the point is knowing more than we did before. We do this because we are curious and want to discover new things. That's the essence of what science is all about."

NTWA

Ultra-small and Ultra–fast Electro-optic Modulator

Due to the voltage applied, a beam of light (top left) is modulated
by the digital bits (bottom right) of the converter (yellow). An electrical
signal is converted into an optical signal. (Graphics: A. Melikyan/KIT)

Nature Photonics Magazine Presents a World-record Micrometer-sized Converter of Electrical into Optical Signals / Future Energy-efficient Chip-to-chip Optical Communication Links

Thanks to optical signals, mails and data can be transmitted rapidly around the globe. But also exchange of digital information between electronic chips may be accelerated and energy efficiency might be increased by using optical signals. However, this would require simple methods to switch from electrical to optical signals. In the Nature Photonics magazine, researchers now present a device of 29 µm in length, which converts signals at a rate of about 40 gigabits per second. It is the most compact high-speed phase modulator in the world. DOI: 10.1038/NPHOTON.2014.9.

“Conversion of electrical into optical signals happens closer to the processor,” Juerg Leuthold says. He coordinated the research project at the Karlsruhe Institute of Technology and has meanwhile moved to the ETH Zurich. “As a result, speed gains are achieved and conduction losses can be prevented. This might reduce energy consumption of the growing information technology.”

The electro-optical converter consists of two parallel gold electrodes of about 29 µm in length, which is one third of the diameter of a human hair. The electrodes are separated by a gap of about one tenth of a micrometer in width. The voltage applied to the electrodes is synchronized with the digital data. The gap is filled with an electro-optical polymer, whose refraction index changes as a function of the applied voltage. “A continuous beam of light from the silicon waveguide excites electromagnetic surface waves, so-called surface plasmons (SP), in the gap,” Argishti Melikyan, KIT, first author of the publication, explains. “As a result of the voltage applied to the polymer, the phase of the SP is modulated. At the end of the device, the modulated SP enter the exit silicon waveguide in the form of a modulated beam of light. In this way, the data bits are encoded in the phase of the light.”

Their recent results revealed that the electro-optic modulator reliably converts data flows of about 40 gigabits per second. It uses the infrared light of 1480 – 1600 nanometers in wavelength usually encountered in the broadband glass fiber network. Even temperatures of up to 85°C do not cause any operation failures. The presented device is the most compact high-speed phase modulator in the world. It can be produced by well-established CMOS fabrication processes. Integration into current chip architectures is hence possible. “The device combines many advantages of other systems, such as a high modulation speed, compact design, and energy efficiency. In the future, plasmonic devices might be used for signal processing in the terahertz range,” says Christian Koos, spokesperson of KIT’s Helmholtz International Research School of Teratronics (HIRST), which focuses on merging photonic and electronic techniques for high-speed signal processing. ”Hundreds of plasmonic modulators might fit on a chip and data rates in the range of terabits per second might be reached.”

Presently, information and communication systems consume about 10 percent of the electricity in Germany. This includes computers and smartphones of individual users as well as servers at large computing centers. As data traffic grows exponentially, new approaches are required to increasing the capacity of such systems and reducing their energy consumption at the same time. Plasmonic components might be of decisive importance in this respect.

The present paper is part of the EU project NAVOLCHI, Nano Scale Disruptive Silicon-Plasmonic Platform for Chip-to-Chip Interconnection. This project is aimed at using the interaction of light and electrons in metal surfaces for the development of novel components for data transmission between chips. “Conventional electric chip-to-chip data transmission reaches its limits,” says the present project coordinator Manfred Kohl, KIT. “NAVOLCHI is about to overcome those limits using optical technology.” It is funded under the 7th Research Framework Programme of the EU and has a budget of EUR 3.4 million.

For more information on the NAVOLCHI project, clickhttp://www.imt.kit.edu/projects/navolchi/ 

High-speed plasmonic phase modulators, A. Melikyan, L. Alloatti, A. Muslija, D. Hillerkuss, P. C. Schindler, J. Li, R. Palmer, D. Korn, S. Muehlbrandt, D. Van Thourhout, B. Chen, R. Dinu, M. Sommer, C. Koos, M. Kohl, W. Freude, and J. Leuthold, nature photonics AOP, DOI: 10.1038/NPHOTON.2014.9

http://www.nature.com/nphoton/index.html 

Karlsruhe Institute of Technology (KIT) is a public corporation according to the legislation of the state of Baden-Württemberg. It fulfills the mission of a university and the mission of a national research center of the Helmholtz Association. Research activities focus on energy, the natural and built environment as well as on society and technology and cover the whole range extending from fundamental aspects to application. With about 9000 employees, including nearly 6000 staff members in the science and education sector, and 24000 students, KIT is one of the biggest research and education institutions in Europe. Work of KIT is based on the knowledge triangle of research, teaching, and innovation.

Source: http://www.kit.edu/visit/pi_2014_14701.php